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A combination of organoboron and radical chemistry generates unusual trans-selectivity in hydroboration of alkynes. The use of N-heterocyclic carbene boranes is key to the success of this chemical ...
Radical trans-Hydroboration of Alkynes with N-Heterocyclic Carbene Boranes. Angewandte Chemie International Edition, 2018; 57 (30): 9485 DOI: 10.1002/anie.201804515 ...